It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hydrogen induced cracking hic testing of low alloy steel. The model assumes that the extension of an embedded circular crack results from accumulation of internal hydrogen pressure that produces a rise of the stress intensity factor in excess of the plane. Hydrogen partial pressure temperature gas impurities. Effect of hydrogen partial pressure on the hydrogen. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. H2s partial pressures and the lowest ph values aqueous medium acidities. Co2 partial pressure under 2 psia no corrosion protection is used with no evidence of downhole corrosion. Roles of microalloying elements in hydrogen induced.
Sulfide stress cracking ssc vs hydrogen induced cracking. The susceptibility of carbon steel to hic can be mitigated by controlling the chemical composition in particular reducing the concentration of manganese sulphide. In such cases the cathodic reaction aggravates the cracking. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking. Defects hydrogen cracks in steels identification twi. H 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. What is the partial pressure of hydrogen gas in units of mmhg. Effect of hydrogen partial pressure on the hydrogen embrittlement. Hydrogeninduced crack growth rate in steel plates exposed to. A metallographic analysis of these steels was performed before and after nace tm0284 standard testing. In this issue, the characteristic features and principal causes of hydrogen cracks are described.
The susceptibility of carbon steel to hic can be mitigated by controlling the chemical composition in particular reducing the concentration of manganese sulphide inclusions in the steel. Hydrogen induced cracking hic is still a challenging issue that requires careful assessment and utilization of test validation measures. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang dept. Corrosion loops were established for the sour environment and. This is a problem commonly found in wet h2ssour service operating environments such as in the oil, gas and petrochemical industry. Hydrogen induced cracks either follow a linear or stepwise path within the material, hence the term stepwise cracking.
Particularly common to the oil and gas industry where the use of steel pressure vessels is widespread, the risk of this should be considered when hydrogen sulphide partial pressure becomes greater than 3. Hydrogeninduced cracking hic is still a challenging issue that requires careful assessment and utilization of test validation measures. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering. Effects of h2s partial pressure and ph of test solution on. This pressure can increase to levels where the metal has reduced ductility, toughness, and tensile strength, up to the point where it cracks open hydrogeninduced cracking, or hic. Hydrogen cracking its causes, costs and future occurrence. A mathematical model was proposed for determining the crack growth rate of hydrogeninduced cracking hic in steel plates exposed to a sour gas. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Thus hydrogen induced blistering can be seen as a special case of the plane pressure mechanism of hydrogen embrittlement, where high pressure hydrogen forms in. However, under certain stress and material conditions, the cracks can be arranged in a ladderlike array known as stress.
Combatting the problem of hydrogen induced cracking in sour service, hic steel plate is carbon steel plates which are tested to assess the susceptibility of the material to hydrogen induced cracking. At constant ph and hydrogen sulphide partial pressure ph2s. They also provided guidance for the selection and specification of sscresistant materials when the h 2 s thresholds were exceeded. Gases dissolve, diffuse, and react according to their partial pressures, and not according to their concentrations in gas mixtures or liquids.
Combining action of atomic hydrogen into hydrogen gas is a. Wet hydrogen sulfide service sour wet hydrogen sulfide h2s service as defined by nace mr0175 iso 15156, occurs when a gas stream h 2s partial pressure exceeds 0. Acid gas corrosion research at curtin curtin corrosion centre houses state of the art research facilities that can simulate complex operating conditions. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Susceptibility to hydrogen induced cracking of api 5l b and x52ms lowcarbon steels in nace 177 a, 177b, and 284b solutions has been investigated by the present work. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Sulfide stress cracking mostly occurs in very highly acidic environments. The same way you calculate the partial pressure of any other gas explanation. The critical partial pressure of h2s for hydrogen induced cracking to occur is. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Co2 partial pressure 5 to 20 psia most fields in this group used inhibitor batch treatment since startup. Hydrogeninduced crack growth rate in steel plates exposed.
Hydrogen embrittlement, also called hydrogen stress cracking or hydrogen induced cracking, is a condition of low ductility in metals resulting from the absorption of hydrogen. Hydrogen induced cracking hic testing of low alloy steel in. The pressure of the hydrogen gas causes localized internal cracks, known as. Sulfide stress cracking has special importance in the gas and oil industry, as the materials being processed there natural. Solubility of hydrogen increases at higher temperatures. Corrosion and hydrogen permeation in h 2 s environments. Effect of hydrogen partial pressure on the hydrogen embrittlement susceptibility of type304 stainless steel in highpressure h2ar mixed gas. Hydrogeninduced cracking an overview sciencedirect topics. Corrosion products were characterized by scanning electron microscopy and xray dispersive energy spectrometry, which were. Hydrogen induced cracking in carbon steel in sour service is a common damage mechanism. Adsorbed hydrogen species recombine to form hydrogen molecules, creating pressure from within the metal.
Nayef ma, abdullah aa 2019 the effect of the partial pressure of h 2 s and c o 2 on the permeation of hydrogen in carbon steel by using pressure buildup techniques. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Corrosionpedia what is hydrogeninduced cracking hic. Specifying valves for hydrogen service valve magazine. Particularly common to the oil and gas industry where the use of steel pressure vessels is widespread, the risk of this should be considered when hydrogen sulphide partial pressure becomes greater than. High partial pressure h2s pipelines pipelines, piping.
At high temperature and high hydrogen partial pressure, hydrogen can diffuse into carbon steel alloys. However, the test environment of nace tm028496 standard hic test method is unnecessarily severe than. Hydrogen induced cracking of hard materials zthe refining industry has had very few cases of hydrogen related cracking in pure hydrogen service. Hic steel hydrogen induced cracking supplier company. Hydrogen induced cracking hic in the oil and gas industry. A detailed assessment study was conducted in this plant pertaining to hydrogen induced cracking hic. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. A saudi aramco gas processing plant commissioned in 1980 to process wet sour gas streams and produce dry sweet sales gas in addition natural gas liquid ngl. H2s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking.
Hydrogen induced cracking hic in the oil and gas industry particularly common to the oil and gas industry where the use of steel pressure vessels is widespread, the risk of this should be considered when hydrogen sulphide partial pressure becomes greater than 3. The presence of high or low ph can greatly increase the severitycorrosiveness of sour environments. Equivalently, low temperature hydrogen induced cracking was also noticed in inconel 718. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal.
As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Over time, the metal becomes so brittle that it cracks. K magnitude, hydrogen partial pressure, loading frequency, gas composition, stress ratio, microstructures, base and weld metals and temperature. Hydrogen embrittlement is the process by which metals become brittle and fracture due to the introduction and subsequent diffusion of hydrogen into the metal. For hydrogen induced cracking to take place, individual hydrogen atoms must cluster at the surface of the metal to create hydrogen molecules. The original and subsequent editions of nace mr0175 established limits of h 2 s partial pressure above which precautions against sulfide stresscracking ssc were always considered necessary. The critical partial pressure of h 2 s for hydrogen induced cracking to occur is about 0. A comparative study of hydrogeninduced cracking resistances of.
Alireza bahadori phd, ceng, micheme, cpeng, mieaust, rpeq, in oil and gas pipelines and piping systems, 2017. A mathematical model was proposed for determining the crack growth rate of hydrogen induced cracking hic in steel plates exposed to a sour gas. Bai p, zheng s, chen c 2015 electrochemical characteristics of the early corrosion stages of api x52 steel. Corrosion and hydrogen permeation in h 2 s environments with. Hydrogen induced cracking steel features, applications. The equilibrium pressure of the molecular hydrogen in the void, which is in contact with the atomic hydrogen in the surrounding metal, is great enough to rupture any metal or alloy. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Process hydrogen is introduced to the surface of a metal and individual hydrogen atoms diffuse through the metal.
Sulfide stress cracking ssc also known as sour gas cracking sour gas. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. Element offers hydrogen induced corrosion hic tests to accurately assess the. Stress corrosion cracking behavior of nickel base alloys. Hydrogen cracking may also be called cold cracking or delayed cracking.
The pressure of the hydrogen gas causes localized internal cracks, known as hydrogen induced cracks. Detection of hydrogen induced cracks during inservice. Hydrogen induced cracking safe materials operating limits. Corrosion products were characterized by scanning electron microscopy and xray dispersive. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials.
Plates of high strength, low alloy hsla steel jisg3115 spv50q were found to be susceptible to sulfide stress cracking and hydrogeninduced cracking hic in wet hsub 2s. H2s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Much of the pipe was x60 36 diameter and often of 5 8 wall thickness. Influence of h2s partial pressure on the corrosion. Sour gas cracking or sulfide stress cracking at high hydrogen sulfide h 2 s partial pressure sour gas cracking, also known as sulfide stress cracking ssc, is the deterioration of metal due to contact with hydrogen sulfide h 2 s and moisture.
Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. The factors that affect hydrogen induced cracking are discussed in table 2. Types of corrosion materials selection guide swagelok. In ssrts in 5%h 2ar gas, which is the fundamental environment, the relative reduction of area was 1. During the construction of the initial gas feeder mains in the uk in the late 60s, following the discovery of gas in the north sea, there were many delays due to hydrogen cracking. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Roles of microalloying elements in hydrogen induced cracking.
The original and subsequent editions of nace mr0175 established limits of h 2 s partial pressure above which precautions against sulfide stress cracking ssc were always considered necessary. As we know that both form of cracking are due to the absorption of atomic hydrogen that. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. However, under certain stress and material conditions, the cracks can be arranged in a ladderlike array known as stress orientated hydrogen induced cracking sohic. Material selection for sour service environment pipeline. Critical hydrogen partial pressure in hydrogen embrittlement. Furthermore, the risk of hydrogen induced cracking is present even at partial pressure of h 2 s pph2s below 0.
A comparative study of hydrogeninduced cracking resistances. Processes or conditions involving wet hydrogen sulfide, i. This clustering produces pressure in the metal which results in the metal losing ductility, toughness and tensile strength. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Corrosion standard tests of carbon steels to be used in oil and gas production establish specific conditions for ph, temperature, h2s partial pressure, and time of. How do you calculate the partial pressure of hydrogen gas.
This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Inversely proportioned to increasing temperature above room temperature 25 degrees c. In order to use linepipe steels properly according to actual. The diffusion coefficient for the hydrogen atom in the spv50q steel was determined at 2560 c and the activation energy for diffusion was 24. Hydrogen embrittlement is mainly a problem in steels with ultimate tensile strength greater than 90 ksi, although a number of additional alloys are susceptible. Hydrogen induced cracking hic remains a prominent issue for oil. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. However, the test environment of nace tm028496 standard hic test method is unnecessarily severe than that of actual sour service conditions. Hydrogen induced cracking hic of line pipe steel was investigated through immersion testing and hydrogen permeation measurements.
The partial pressure of a gas is a measure of thermodynamic activity of the gass molecules. An electron backscatter diffraction ebsd micrograph of hic induced by laboratory testing of an x52 alloy is shown in fig. Hydrogeninduced cracking hic is still a challenging issue that requires. Jul 29, 2019 the critical partial pressure of h 2 s for hydrogen induced cracking to occur is about 0. Handbook of materials failure analysis with case studies from the oil and gas industry, 2016.
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